Impact of Lightning‐Induced Nitrogen Oxides Over and Around the Tibetan Plateau on the Tibetan Plateau Ozone Valley

对流层 平流层 高原(数学) 闪电(连接器) 大气科学 高度(三角形) 活性氮 臭氧 对流层臭氧 季风 环境科学 气候学 氮气 化学 气象学 地质学 地理 物理 数学 几何学 数学分析 功率(物理) 有机化学 量子力学
作者
Zhou Liu,Fengxia Guo,Yuqiang Zhang,Zeyi Wu,Xian Lu,Jie Deng,Ke Chen,Qingyuan Wang,Miao He
出处
期刊:Journal Of Geophysical Research: Atmospheres [Wiley]
卷期号:129 (1) 被引量:3
标识
DOI:10.1029/2023jd039575
摘要

Abstract Lightning‐induced nitrogen oxides (LNO x ) can affect ozone (O 3 ) through photochemical processes. However, the impact of LNO x on the Tibetan Plateau (TP) O 3 valley, an area with a lower O 3 column compared to surrounding areas, remains controversial. Prior to this study, the impact of monsoonal transport on LNO x and related effects on the TP O 3 valley has been overlooked. The objectives of this study are to differentiate between locally generated LNO x and monsoon‐transported LNO x over the TP and to evaluate their impacts on tropospheric NO x vertical column density, tropospheric column O 3 , and O 3 at different altitudes. The Weather Research and Forecasting model coupled with Chemistry model was used to replicate LNO x , NO x , and O 3 over the TP during July 2010, for which nesting techniques and sensitivity experiments were implemented. The findings emphasize the importance of LNO x as a source of NO x in this region, with nonlocal lightning activity being the primary source. Conversely, the influence of locally generated LNO x on NO x levels over the TP is comparatively minor. Overall, LNO x contributes to an increase in O 3 over the TP, but one order lower than the O 3 depletion. The impact of LNO x on O 3 varies across different altitude ranges; it is broadly “C” shaped, reflecting increase in O 3 at near‐surface and in upper troposphere–lower stratosphere (UTLS) regions and decrease in the middle troposphere. The increase in surface‐level O 3 over the TP is mainly caused by monsoon‐transported LNO x , while locally generated LNO x also plays a crucial role in O 3 formation in the UTLS region.
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