Amorphous titanium dioxide with abundant defects induced by incorporation of silicon dioxide: A potential non-radical activator of hydrogen peroxide

Catalysts based on titanium dioxide (TiO2) have demonstrated a significant potential for oxidizing intractable organic pollutants in heterogenous Fenton-like reactions, even in the absence of light irradiation. In this study, defective amorphous TiO2 enriched Ti3+ and oxygen vacancies (Ov) was synthesized by incorporation of silicon dioxide (SiO2) via a simple sol–gel method. Based on a systematic exploration, an optimal amount of SiO2 was found to be crucial in promoting the formation of Ov and Ti3+, which was achieved by maximizing the non-hexacoordinate structure (Ti4/5/7c) in amorphous TiO2. Furthermore, an unusual singlet oxygen (1O2) based non-radical mechanism was confirmed. It was proposed that the hydroxyl radicals (•OH) produced by Ti3+ active sites during hydrogen peroxide (H2O2) activation may adsorb on the TiO2 surface for extended periods, owing to their favorable interactions with the surface Ov and hydroxyl groups (–OH), thus facilitating their transformation to 1O2. Moreover, the optimized catalyst exhibited favorably catalytic performance across a broad pH range (3–11), making it a promising candidate for applications in rigorous environmental conditions.