化学
镧系元素
齿合度
光致发光
离子
结晶学
星团(航天器)
镧系收缩
发光
配体(生物化学)
Atom(片上系统)
激发
立体化学
晶体结构
有机化学
受体
程序设计语言
物理
嵌入式系统
工程类
光学
电气工程
量子力学
生物化学
光电子学
计算机科学
作者
Xue-Tao Wang,Lan-Tao Cheng,Cheng Chen,Lingyun Cao,Jun Zheng,Xiu-Ying Zheng
标识
DOI:10.1021/acs.inorgchem.2c02991
摘要
Three pairs of chiral Ln-Ag(I) clusters d/l-Ln3Ag5 with C3 symmetry were prepared by d/l-penicillamine as multidentate ligand bridged Ln3+ and Ag(I) ions. The chiral ligand induced the molecular cluster to be chiral, and the CD spectra of the chiral compounds d/l-Ln3Ag5 were slightly blue-shifted due to the lanthanide contraction. The studies of optical properties indicated that tunable photoluminescence from {AgS}-to-Ln3+ was achieved by introducing Ln3+ ions with different emission bands or regulating various excitation light.
科研通智能强力驱动
Strongly Powered by AbleSci AI