热电效应
材料科学
塞贝克系数
钙钛矿(结构)
卤化物
光电子学
电阻率和电导率
能量转换效率
热稳定性
热导率
热电材料
纳米技术
化学工程
化学
结晶学
无机化学
热力学
复合材料
电气工程
工程类
物理
作者
Sheng‐Ning Hsu,Wenchao Zhao,Yao Gao,Akriti,Mauricio Segovia,Xianfan Xu,Bryan W. Boudouris,Letian Dou
出处
期刊:Nano Letters
[American Chemical Society]
日期:2021-09-01
卷期号:21 (18): 7839-7844
被引量:27
标识
DOI:10.1021/acs.nanolett.1c02890
摘要
Sn-based halide perovskites are promising for thermoelectric (TE) device applications because of their high electrical conductivity as well as the low thermal conductivity associated with their soft lattices. However, conventional three-dimensional Sn-based perovskites are not stable under typical TE device operating conditions. Here, we report a stable two-dimensional Sn-based perovskite for thermoelectric energy conversion by incorporating bulky conjugated ligands. We demonstrate a thin film with a large power factor of 5.42 ± 3.07 (average) and 7.07 (champion) μW m–1 K–2 at 343 K with an electrical conductivity of 5.07 S cm–1 and a Seebeck coefficient of 118.1 μV K–1. Importantly, these thin films show excellent operational stability (i.e., for over 100 h) at 313 K. This work suggests that the novel hybrid two-dimensional perovskites are a promising platform for thermoelectric energy conversion applications.
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