Fe─N 4 ‐Anchored Carbon Layer Patched TiO 2 Cavities to Construct an “In‐Lattice Heterojunction” for Enhanced Photocatalytic Nitrogen Reduction Reactions

Abstract Efficient charge separation and carrier transfer are critical determinants of the performance of photocatalysts for nitrogen reduction reactions (NRR) which are critical for agricultural and chemical industries. In this study, a novel type of heterostructure, termed an “In‐Lattice heterojunction”, has been constructed by introducing a Fe─N 4 ‐anchored carbon layer (Fe─N─C) onto the surface of defective TiO 2 (D‐TiO 2 ), as well as implanting it into the cavities of D‐TiO 2 . The in‐lattice heterojunction, defined as FNCTO, achieves efficient radial carrier transfer along the Ti─C─N─Fe in‐lattice atomic channel and greatly promoted N 2 adsorption benefiting photocatalytic NRR. Thus, FNCTO exhibits an excellent photocatalytic N 2 reduct`ion into NH 3 activity (88 µmol g −1 h −1 ), obviously higher than that of Fe─N─C sites on noncavity P25, illustrating the crucial role of cavity patch induced in‐lattice heterojunction. This study paves a way for the development of high‐performance Fe─N─C atomic photocatalysts based on noncarbon materials.