A Review of Phase-Change Material-Based Thermal Batteries for Sustainable Energy Storage of Solar Photovoltaic Systems Coupled to Heat Pumps in the Building Sector

Buildings account for about a third of global energy and it is thus imperative to eliminate the use of fossil fuels to power and provide for their thermal needs. Solar photovoltaic (PV) technology can provide power and with electrification, heating/cooling, but there is often a load mismatch with the intermittent solar supply. Electric batteries can overcome this challenge at high solar penetration rates but are still capital-intensive. A promising solution is thermal energy storage (TES), which has a low cost per unit of energy. This review provides an in-depth analysis of TES but specifically focuses on phase change material (PCM)-based TES, and its significance in the building sector. The classification, characterization, properties, applications, challenges, and modeling of PCM-TES are detailed. Finally, the potential for integrating TES with PV and heat pump (HP) technologies to decarbonize the residential sector is detailed. Although many studies show proof of carbon reduction for the individual and coupled systems, the integration of PV+HP+PCM-TES systems as a whole unit has not been developed to achieve carbon neutrality and facilitate net zero emission goals. Overall, there is still a lack of available literature and experimental datasets for these complex systems which are needed to develop models for global implementation as well as studies to quantify their economic and environmental performance.