Iron, Sulfur, and Carbon Dynamics Collectively Regulate the Fate of Cadmium over the Sulfidation-Reoxidation Cycle

. Released Cd from CdS oxidation was predominantly readsorbed on Fe(III) oxides. Additionally, released Cd was partially structurally incorporated into newly formed Fe(III) oxides while some CdS was encapsulated within Fe(III) oxide aggregates. However, OM interactions with Fe(III) oxides reduced the formation of these Cd species. These findings provide insights into the molecular-scale mechanisms governing Cd dynamics in redox-dynamic environments.