Abstract 2, 5‐Diacetyl‐1‐cyclopentanone and 2, 5‐dibenzoyl‐1‐cyclopentanone are obtained by base induced cyclisations of ethyl 2‐acetyl‐6‐oxo‐heptanoate and ethyl 2, 5‐dibenzoyl‐pentanoate. Competing with this condensation aldol type cyclisations occur.