Plasticizing and thermal stabilizing effect of bio‐based epoxidized cardanol esters on PVC

Abstract Poly(vinyl chloride) (PVC) is a widely used plastics in different industries. It is an intrinsically hard and brittle polymer and requires the use of plasticizers to improve the processability. Commonly used phthalate‐based plasticizers have serious toxicity issues and we present alternatives based on epoxidized soybean oil (ESO) and epoxidized cardanol esters (ECEs). ECEs are synthesized from cardanol and three fatty acids (oleic, ricinoleic, and myristic) using 1‐ethyl‐3‐(3‐dimethylaminopropyl) carbodiimide (EDC) as a coupling agent. Their structure and purity are confirmed by Fourier transform infrared spectroscopy (FTIR) and Nuclear magnetic resonance. Moreover, plasticized PVC films are prepared using a solvent‐free method. The replacement of 10 phr of ESO with 5 phr of ECE improves the plasticizing power due to the co‐solvency effect. Mechanical properties and thermal stability of plasticized PVC films are correlated with the chain length and the number of epoxy groups in ECE. The best plasticizing effect is observed for epoxidized cardanol‐myristate (ECD‐MA). ECD‐MA as a shorter‐chain secondary plasticizer is more compatible with ESO and allows higher conformational mobility of PVC chains. PVC/30ESO/5ECD‐MA polymer exhibits an exceptionally high initial thermal decomposition temperature (314.4°C) while preserving moderate ductility and tensile strength (263.4% and 23.3 MPa). Overall, this study highlights the potential applicability of ECD‐MA in combination with ESO as a sustainable, bio‐based plasticizer and heat stabilizer for flexible PVC products.