Two σ- and two π-dative quadruple bonds between the s-block element and transition metal in [BeM(CO)4; M = Fe − Os]

The bonding interaction between the metal fragment M(CO) 4 and beryllium in BeM(CO) 4 (M = Fe, Ru, and Os) can be best described by dative quadruple bonds, viz. , two σ and two π dative bonds.