假电容器
超级电容器
介电谱
循环伏安法
尖晶石
材料科学
计时安培法
石墨烯
氧化物
纳米复合材料
化学工程
电化学
电极
电容
水热合成
纳米材料
热液循环
纳米技术
化学
冶金
物理化学
工程类
作者
Hafiz Muhammad Tahir Farid,Soumaya Gouadria,S.M. Al-Moayid,H. Algarni,Mohd Zahid Ansari,H. Elhosiny Ali
标识
DOI:10.1016/j.est.2023.107394
摘要
Spinel oxide nanomaterial based on pseudocapacitor electrodes is a superior remedy for the present energy problem. In this study, CuCo2O4 and reduced graphene oxide (rGO) are mixed utilizing a clean hydrothermal strategy. The characteristics of synthesized electrocatalysts were examined by employing microscopic and spectroscopic techniques. Galvanostatic charge-discharge techniques (GCD), cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and chronoamperometry (CA) were used to analyze the electrocatalytic behavior of all synthesized materials. The electrochemical analysis showed that the incorporation of rGO rises the discharge duration interval resultant enhances the specific capacitance (Cs) and improves the overall stable behavior of the CuCo2O4 electrocatalytic materials. At 2.0 A g−1, the electrochemical findings of spinel/rGO nanohybrid show Cs of 1372.93 F g−1, energy density (Ed) of 70.02 Wh Kg−1 and power density (Pd) of 606 W Kg−1 at 2 A g−1. The nanohybrid showed 96.35 % capacitance retention over 5000th cycles and remained stable for 40 h. However, adjustments to the electrical and structural arrangement, morphology, or doping technique improved the capacitive activity of the produced electrode.
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