Facile synthesis to tune size, textural properties and fiber density of dendritic fibrous nanosilica for applications in catalysis and CO2 capture

Morphology-controlled nanomaterials such as silica play a critical role in the development of technologies for use in the fields of energy, environment (water and air pollution) and health. Since the discovery of Stober’s silica, followed by the discovery of mesoporous silica materials (MSNs) such as MCM-41 and SBA-15, a surge in the design and synthesis of nanosilica with various sizes, shapes, morphologies and textural properties (surface area, pore size and pore volume) has occurred. Dendritic fibrous nanosilica (DFNS; also known as KCC-1) is one of the recent discoveries in morphology-controlled nanomaterials. DFNS shows exceptional performance in large numbers of fields, including catalysis, gas capture, solar energy harvest, energy storage, sensors and biomedical applications. This material possesses a unique fibrous morphology, unlike the tubular porous structure of various conventional silica materials. It has a high surface area to volume ratio, with improved accessibility to the internal surface, tunable pore size and pore volume, controllable particle size and, importantly, improved stability. However, synthesis of DFNS with controllable size, textural properties and fiber density is still tricky because of several of the steps involved. This protocol provides a comprehensive step-wise description of DFNS synthesis and advice regarding how to control size, surface area, pore size, pore volume and fiber density. We also provide details of how to apply DFNS in catalysis and CO2 capture. Detailed characterization protocols for these materials using scanning electron microscopy (SEM), transmission electron microscopy (TEM), nitrogen adsorption and thermal gravimetric analysis (TGA) studies are also provided. This protocol describes how to synthesize high-surface-area dendritic fibrous nanosilica (DFNS) with tunable sizes, textural properties and fiber density at different scales. It also includes the application of DFNSs in catalysis (Suzuki coupling) and CO2 capture.