石墨烯
流变学
氧化物
兴奋剂
材料科学
粘弹性
剪切速率
动态力学分析
结晶度
化学工程
剪切减薄
复合材料
纳米技术
聚合物
光电子学
工程类
冶金
作者
Mit Rita Goswami,Prayas Singh,Pankaj Chamoli,Sumit Bhardwaj,K. K. Raina,Ravi K. Shukla
标识
DOI:10.1080/01932691.2021.2013862
摘要
Poly (vinylidene fluoride) (GO/PVDF) nanocomposites (NCs) are prepared via dispersing 1 mg and 5 mg of graphene oxide (GO) sheets in PVDF/Tetrahydrofuran (THF) and 2-dimethylformamide (DMF) solution. X-Ray Diffraction (XRD) and FTIR analysis confirm that NCs exhibits β-phase and their crystallinity increased with GO doping. This paper presents a solution method for GO/PVDF NCs preparation and explored their shear and dynamic rheology at room temperature than that of melt state/rheology. GO/PVDF NCs show shear-thinning to discontinuous shear thickening (DST) behavior, increase of the flow viscosity (20045.16 mPa.s and 50311.81 mPa.s for 1 mg and 5 mg) and altered critical shear rate as a function of increasing GO doping concentration. The observed rheological behaviors could be a result of hydrodynamic forces. Dynamic rheology and relaxation frequency and time measurements confirm that the doping GO leads to the viscoelastic behavior in NCs than that of glassy behavior of neat PVDF. Viscoelastic and gelation properties of GO/PVDF NCs make them potential candidates for lubrication applications.
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