材料科学
正交晶系
带隙
折射率
从头算
密度泛函理论
电子能带结构
晶格常数
凝聚态物理
衰减系数
各向异性
电子结构
态密度
从头算量子化学方法
电介质
直接和间接带隙
分子物理学
光学
计算化学
衍射
光电子学
化学
分子
物理
有机化学
作者
Yunxia Zhang,Li'na Xiao
标识
DOI:10.1149/2162-8777/ac4d7f
摘要
Abstract We report first-principles studies of the structural, elastic, electronic, and optical properties of Mg2GeO4 in orthorhombic structure, including pressure dependence of structural parameters, band structures, density of states, and optical constants up to 20 GPa. The calculated structural parameters are in good agreement with the available experimental values at zero pressure. The mechanical stability of Mg2GeO4 has been confirmed by calculation of the elastic constants and the non-uniform pressure dependence of the lattice parameters may also mean that Mg2GeO4 undergoes anisotropic compression. Meanwhile, the pressure dependence of the electronic band structure, density of states and partial density of states of Mg2GeO4 up to 20 GPa were presented. The band structures show a direct band gap for this compound and the calculated band gaps expend with increasing pressure. Moreover, the evolution of the dielectric function, absorption coefficient (α(ω)), reflectivity (R(ω)), and the real part of the refractive index (n(ω)) at high pressure are also presented. According to our work, we found that the optical absorption spectra of Mg2GeO4 undergo a blue shift with increasing pressure.
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