Controlled crystal facet of tungsten trioxide photoanode to improve on-demand hydrogen peroxide production for in-situ tetracycline degradation

Advanced oxidation processes utilizing hydrogen peroxide (H2O2) are widely employed for the treatment of organic pollutions. However, the conventional anthraquinone method for H2O2 synthesis is unsuitable for this application owing to its hazardous and costly nature. Alternative approaches involve a photoelectrochemical method. Herein, tungsten trioxide (WO3) photoanode has been used for the conversion of H2O into H2O2 through oxidation reaction from a PEC system, simultaneously utilizing in-situ generated hydroxyl (OH•) radicals for tetracycline degradation. By manipulating the ratio of crystal facets between (0 2 0) and (2 0 0) of the WO3 photoanode, a significant improvement in H2O2 production has been achieved by increasing the proportion of (0 2 0) facet. The production rate of WO3 photoanode enriched with the (0 2 0) facet is approximately 1.9 times higher than that enriched with (2 0 0) facet. This enhanced H2O2 production performance can be attributed to the improved formation of OH• radicals and the accelerated desorption of H2O2 on the (0 2 0) facet. Simultaneously, the in-situ generated OH• radicals are applied for tetracycline degradation. Under illumination of sunlight stimulator for 180 min, the optimal photoanode achieves a degradation rate of 86.7% for tetracycline. Furthermore, the resulting chemicals have been analyzed, revealing that C8H10O and C7H8O were formed as the primary products. Notably, these products exhibit significantly lower toxicity compared to tetracycline. This study presents a promising approach for the rational design of WO3 based photoanodes for oxidation reaction, including not only H2O2 production but also the efficient degradation of organic pollutants.