Nitrile glove composition and performance—Substandard properties and inaccurate packaging information

耐久性 丁腈橡胶 极限抗拉强度 聚氯乙烯 丙烯腈 材料科学 复合材料 聚合物 天然橡胶 化学 有机化学 共聚物
作者
Ashley Herkins,Sriloy Dey,D. A. Conroy,Katrina Cornish
出处
期刊:PLOS ONE [Public Library of Science]
卷期号:19 (10): e0312891-e0312891
标识
DOI:10.1371/journal.pone.0312891
摘要

The durability and mechanical properties of synthetic medical gloves, such as those made from nitrile, vary drastically depending on the manufacturer. This study reports the chemical composition of several brands of nitrile gloves via FTIR and solid-state NMR analysis and relates composition to glove durability (found via GAD), mechanical performance (found via Instron), and whether the gloves meet or fail ASTM International standards. Out of the four nitrile examination glove brands tested, American Nitrile Slate brand had superior durability results and was found to be made of acrylonitrile butadiene rubber, as expected. The U.S. Medical glove brand, which was also found to be pure nitrile, had the superior tensile results, consistently reaching over 800% elongation before breaking. Although Restore Touch brand exam gloves were made of nitrile, they exhibited substandard tensile strength and durability due to the thinness of the glove, which barely met the ASTM minimum thickness value. The Vglove brand glove had the overall worst mechanical properties, did not meet ASTM requirements, and had an NMR spectrum consistent with that of a polyvinyl chloride glove, rather than nitrile. Gloves that fail to meet the minimum performance requirements should not be used for medical purposes to protect the health and safety of consumers.

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