四环素
光催化
方案(数学)
降级(电信)
化学
光降解
异质结
可见光谱
罗丹明B
化学工程
材料科学
催化作用
环境化学
纳米技术
复合数
甲基橙
生化工程
X射线光电子能谱
计算机科学
工程类
电信
数学
有机化学
数学分析
抗生素
生物化学
作者
Shuqu Zhang,Zhifeng Zhang,Bing Li,Weili Dai,Yanmei Si,Lixia Yang,Shenglian Luo
标识
DOI:10.1016/j.jcis.2020.10.140
摘要
Z-scheme photocatalyst preserved with superior oxidicability is an innovative photocatalyst system that can be used for efficient photocatalytic detoxification of antibiotics. In this study, Z-scheme Ag3PO4@ZnIn2S4 photocatalyst was constructed by decorating Ag3PO4 nanoparticles on ZnIn2S4 nanoscopariums. ZnIn2S4 nanoscopariums were prepared by self-templated strategy and given hierarchical structures. The hierarchical Ag3PO4@ZnIn2S4 provides more active sites for generating photogenerated carriers and large surface area for capturing tetracycline. The study results show that Ag3PO4@ZnIn2S4 performed excellently well in the photocatalytic degradation of tetracycline and also in protecting Ag3PO4 nanoparticles from photo-corrosion. The highest removal efficiency (up to 92.3%) was achieved from the optimal composites of Ag3PO4 and ZnIn2S4. In stability tests, Ag3PO4@ZnIn2S4 did not reduce the photocatalytic activity of degrading tetracycline after five successive runs. Active radical identification proves that the transfer behavior of electron and hole over Ag3PO4@ZnIn2S4 follows a direct Z-scheme mechanism. Furthermore, the transformation pathway for degrading tetracycline was proposed by combining the Fukui index prediction with Mass Spectra identification of intermediates. This work presents in-depth sights into a regulated degradation pathway from theoretical prediction and practical identification based on innovative Z-scheme photocatalyst.
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