乙二醇
化学
乙烯
高分子化学
8-羟基喹啉
螯合作用
高分子
核化学
羧酸
吡啶
核磁共振波谱
质谱法
有机化学
色谱法
生物化学
催化作用
作者
Rositsa Mladenova,Ts. Petrova,Nevena Manolova,Miléna Ignatova,Iliya Rashkov,Przemysław Kubisa
标识
DOI:10.1106/ad9e-dqyk-579v-ht7a
摘要
New macromolecular chelators were synthesized under mild conditions by reaction of 8-hydroxyquinoline-2-carboxylic acid (8Q2COOH) with polyethers having amino end-groups (Jeffamines ED®) or poly(ethylene glycol)s in the presence of dicyclohexylcarbodiimide and dimethylamino-pyridine. The prepared amides (8Q2CONH-POE) and esters (8Q2COO-POE) were characterized by SEC, DSC, IR, 1 H and 13 C NMR spectroscopy, and MALDI-TOF mass spectrometry. It was found that the polyethers had 8-hydroxy-2-quinolinyl end groups and formed complexes with Fe 3+ ions. The obtained complexes were studied with IR spectroscopy and DSC. The plant tests showed that the Fe 3+ complex of 8Q2CONH-POE 2000 had high efficacy in the remedy of iron-deficient maize plants under hydroponic conditions.
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