化学
硼氢化钠
区域选择性
催化作用
甲醇
共轭体系
硼氢化
药物化学
镍
劈理(地质)
有机化学
断裂(地质)
工程类
岩土工程
聚合物
作者
Biaolin Yin,Congbi Cai,Jin‐Qiang Lai,Ze‐Ren Zhang,Li Huang,Li‐Wen Xu,Huanfeng Jiang
标识
DOI:10.1002/adsc.201100612
摘要
Abstract The regioslective reduction of electron‐rich dienes to monoolefins and the reductive cleavage of allyl esters were fulfilled by employing a sodium borohydride‐nickel chloride‐methanol catalytic system with exceedingly simple manipulations and high functional group tolerability. Both of the reductive reactions may involve π‐allylnickel intermediates generated from fresh nickel boride.
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