Highly Stretchable, Adhesive Ionic Liquid-Containing Nanocomposite Hydrogel for Self-Powered Multifunctional Strain Sensors with Temperature Tolerance

The demand for wearable sensors consisting of multifunctional conductive hydrogels with fatigue resistance and adhesion properties is rising. More importantly, it is necessary to improve the freezing tolerance and dehydration resistance of hydrogels to avoid performance degradation in harsh environments. Herein, a robust nanocomposite ionogel was fabricated in [EMIM][Cl] ionic liquid and clay nanosheets were used as physical cross-linkers through rapid UV polymerization. The excellent mechanical properties, repeated self-adhesion to various substrates, freezing tolerance, and anti-drying properties were integrated into the nanocomposite ionic liquid hydrogel. The addition of clay nanosheets Laponite XLG endowed the ionogel with a high stretchability of up to 1200% and a tensile strength of up to 0.14 MPa, and the ionogel could be recovered when the external force was released. Ascribing to ionic liquids, the nanocomposite ionogel displayed ionic conductivity and temperature tolerance. An ionogel battery with a 0.72 V output voltage was formed by assembling the ionogel with a layer of zinc and copper sheet on each side to realize the conversion from chemical energy to electrical energy. The maximum voltage could reach 2.8 V when the four units are combined, which could provide energy for an LED bulb and could be used as a self-powered strain sensor under harsh conditions. In this work, a multifunctional ionogel self-powered sensor is proposed, which has potential applications in the fields of electronic skin, human-machine interaction, and biosensors over a wide temperature range.