化学
铈
催化作用
环加成
光激发
光催化
电子转移
光化学
组合化学
有机化学
激发态
物理
核物理学
作者
Anhua Hu,Yilin Chen,Jingjing Guo,Na Yu,Qing An,Zhiwei Zuo
摘要
We describe a synergistic utilization of cerium photocatalysis and photoinduced electron transfer catalysis that enables an atom- and step-economical ring expansion of readily available cycloalkanols. This operationally simple protocol provides rapid access to privileged and synthetically challenging bridged lactones. The mild catalytic manifold has been adapted to continuous flow for scale-up applications and employed for the concise synthesis of polycyclic core of nepalactones.
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