光催化
钙钛矿(结构)
量子点
卤化物
量子产额
材料科学
乙腈
产量(工程)
光化学
多孔性
化学工程
纳米技术
化学
无机化学
催化作用
有机化学
复合材料
光学
物理
工程类
荧光
作者
Man Ou,Wenguang Tu,Shengming Yin,Weinan Xing,Shuyang Wu,Haojing Wang,Shipeng Wan,Qin Zhong,Rong Xu
标识
DOI:10.1002/anie.201808930
摘要
Abstract Halide perovskite quantum dots (QDs) have great potential in photocatalytic applications if their low charge transportation efficiency and chemical instability can be overcome. To circumvent these obstacles, we anchored CsPbBr 3 QDs (CPB) on NH x ‐rich porous g‐C 3 N 4 nanosheets (PCN) to construct the composite photocatalysts via N−Br chemical bonding. The 20 CPB‐PCN (20 wt % of QDs) photocatalyst exhibits good stability and an outstanding yield of 149 μmol h −1 g −1 in acetonitrile/water for photocatalytic reduction of CO 2 to CO under visible light irradiation, which is around 15 times higher than that of CsPbBr 3 QDs. This study opens up new possibilities of using halide perovskite QDs for photocatalytic application.
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