电催化剂
抗坏血酸
检出限
纳米线
材料科学
铜
磷化物
尿酸
无机化学
电化学
催化作用
化学
纳米技术
生物化学
色谱法
电极
冶金
物理化学
食品科学
作者
Lisi Xie,Abdullah M. Asiri,Xuping Sun
标识
DOI:10.1016/j.snb.2016.12.093
摘要
The detection of glucose plays a significant role in diagnostics and management of diabetes and it is thus desired to develop non-noble-metal electrocatalyst for nonenzymatic glucose sensing. This work demonstrates the first use of monolithically integrated copper phosphide nanowire on copper foam (Cu3P NW/CF) as an efficient catalyst for electrochemical oxidation of glucose. As a nonenzymatic glucose sensor, this Cu3P NW/CF exhibits a low detection limit of 0.32 μM at a signal-to-noise ratio of 3 with a linear range from 0.005 to 1 mM (R2 = 0.997). It also shows high anti-interference property to other normally co-existing electroactive species including lactose, fructose, ascorbic acid, uric acid, urea, dopiamine, and sucorse as well as excellent resistance to chloride poisoning. Its application for glucose detection in human serum sample is also demonstrated successfully.
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