材料科学
纳米纤维
静电纺丝
极限抗拉强度
韧性
阻燃剂
复合材料
微流控
复合数
延伸率
纳米技术
化学工程
聚合物
工程类
作者
Long Shi,Jiang Zhai,Qing Li,Liangliang Zhu,Xin Zhao,Su Chen,Guo‐Xing Li
摘要
ABSTRACT The poly(butylene adipate‐co‐terephthalate) (PBAT) nanofiber film prepared by electrospinning method exhibits limited application in many fields due to its poor flame retardancy and machinal property, despite being a biodegradable material with exceptional toughness and ductility properties. In this work, we employed microfluidic technology to continuously produce blue fluorescent carbon dots (CDs) on an aluminum‐based microfluidic chip using citrate and ethanolamine as precursors. Subsequently, utilizing microfluidic electrospinning technology, the CDs/PBAT composite nanofiber films with blue fluorescence were prepared in situ reaction. Interestingly, compared to pure PBAT nanofiber membranes, the CDs/PBAT composite nanofiber membranes exhibit a tensile strength of 4.31 MPa, representing a remarkable increase of 3.24 times, and an elongation at break of 491%, indicating an improvement of 1.62 times. More importantly, it had demonstrated that the incorporation of CDs into PBAT can achieve flame‐retardant effects. We firmly believe that the microfluidic strategy could open up a new idea for the synthesis of CDs and point out the direction for the meaningful fabrication of PBAT nanofiber film with high tensile strength and flame‐retardant property.
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