微型多孔材料
异烟酸
研磨
金属有机骨架
材料科学
铜
金属
化学工程
溶剂
化学
吸附
有机化学
无机化学
冶金
工程类
酰肼
作者
Anne Pichon,Ana Lazuen-Garay,Stuart L. James
出处
期刊:CrystEngComm
[The Royal Society of Chemistry]
日期:2006-01-01
卷期号:8 (3): 211-211
被引量:472
摘要
We describe the first solvent-free mechanochemical synthesis of a microporous metal–organic framework [Cu(INA)2] (INA = isonicotinic acid); the product has robust 3-dimensional connectivity and is obtained quantitatively by grinding together copper acetate and isonicotinic acid for 10 minutes without any applied heating—the high efficiency of the synthesis suggests that mechanochemical synthesis should be further investigated as a convenient method for the preparation of microporous metal–organic frameworks (MOFs).
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