普鲁士蓝
磁铁
分子电子学
纳米技术
材料科学
化学物理
分子
化学
物理
物理化学
有机化学
电极
电化学
量子力学
作者
Yulong Huang,Shenqiang Ren
标识
DOI:10.1016/j.apmt.2020.100886
摘要
There is a surge of interest to expand the search for entirely new classes of molecular magnets as the emergence of information storage and quantum computing devices. Prussian blue analogues as a family of molecular magnets are especially attracting wide attention due to their large number of derivatives with a range of magnetic ordering temperature from cryogenic to room temperature. This review presents Prussian blue analogues as multifunctional molecular magnets, which involves the development of molecular magnet syntheses and crystal structures, and magnetic properties under external stimuli. In addition, the porous network structures and vacancy order of Prussian blue analogues present a wide capability to interact with water molecules and gas adsorption. External stimuli, such as thermal, pressure, electric and magnetic field and photoexcitation, play an important role in controlling the hidden states and cooperative phenomena of high temperature molecular magnets based on Prussian blue analogues.
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