化学
结晶学
八面体
堆积
晶体结构
分子
离子
平面的
类型(生物学)
衍射
Crystal(编程语言)
立体化学
计算机图形学(图像)
程序设计语言
有机化学
物理
光学
生物
计算机科学
生态学
作者
Run-Qin Lu,Hu Zhou,Yingying Chen,Jie Xiao,Aihua Yuan
标识
DOI:10.1080/00958971003646514
摘要
The first Hofmann-DMF-type complexes Zn(DMF)2M(CN)4 (M = Ni (1), Pd (2), Pt (3)) have been synthesized by solution diffusion and characterized structurally by single-crystal X-ray diffraction. The structure consists of 2-D corrugated sheets stacking along the a-axis in an ABAB packing mode without interpenetration. The octahedral Zn ions and square-planar M ions occupy special positions of 2/m site symmetry. The DMF, except for six methyl H atoms, lies on a crystallographic mirror plane; the DMF molecules coordinate to axial sites of Zn on both sides of the sheet. The framework of 1 begins to collapse with loss of coordinated DMF.
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