材料科学
石墨烯
超级电容器
电极
纳米技术
氧化物
复合数
储能
化学工程
兴奋剂
电池(电)
电化学
光电子学
复合材料
化学
冶金
量子力学
物理
工程类
物理化学
功率(物理)
作者
Guohong Zhang,Jiale Yang,Haicheng Xuan,Jiangtao Yang,Xiaohong Liang,Yuping Li,Peide Han
标识
DOI:10.1016/j.jallcom.2021.163125
摘要
Transition metal dopant engineering and rational architecture design have been proven to be effective strategies to improve the electrochemical energy storage properties of electrodes. Herein, V-doped NiMn-layered double hydroxide composites were supported on reduced graphene oxide-coated Ni foam (NMV-L/rGO) by a hydrothermal method. The influences of V content on the electrochemical performances of NMV-L/rGO composites were investigated in detail. At an optimal content of V doping (15%), the NMV-L/rGO-15 reveals enhanced electrochemical properties, and it is subsequently applied as the substrate for the electrodeposition of Ni3S2 layer. Benefiting from the collaborative effect of NMV-L/rGO-15, Ni3S2, and rGO materials, as well as the unique hierarchical architecture, excellent electrochemical performance is obtained in the as-prepared Ni3S2 @NMV-L/rGO-15 composite, which exhibits a high specific capacity of 1412.0 C g−1 at 1 A g−1 as well as desirable long-term stability of 89% over 5000 cycles. Furthermore, the as-fabricated battery-supercapacitor hybrid device (BSH) based on Ni3S2 @NMV-L/rGO-15 and activated carbon (AC) electrodes displays a remarkable energy density of 60.0 W h kg−1 at the power density of 849.1 W kg−1 and superior capacity retention of 96% through 7000 cycles. Such excellent results indicate that the Ni3S2 @NMV-L/rGO-15 composite holds great potential as electrode material for high-performance BSHs.
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