MC decomposition and boride formation in a next generation polycrystalline Ni based superalloy during isothermal exposure at 900 °C

Detailed microstructural characterisation of phases present in a next generation polycrystalline Ni based superalloy after thermal exposure at 900 °C was carried out, focusing on carbides and borides. Metastable M5B3 precipitated after 32 h had a stoichiometry of (Cr0.7Mo0.2W0.1)5B3 with substitutions with Ni, Co, Nb and Ta. Fine M23C6 (a = 10.62 Å) was overgrown by metastable M5B3, as shown by rigorous TEM-SAD pattern investigation. The borides were eventually dominated by Mo rich M3B2, at the apparent expense of MC. Decomposition of MC was confirmed; it transformed sequentially to γ and then γ΄. The primary driving force for the MC decomposition was attributed to γ΄ precipitation, increasing its fraction to the thermodynamic equilibrium at 900 °C.