钙钛矿(结构)
桥(图论)
材料科学
分子
工程物理
光电子学
纳米技术
物理
化学
结晶学
医学
量子力学
内科学
作者
Chenxu Zhao,Qi Zhang,Yin-Long Lyu,Xinxin Lian,Kongxiang Wang,Shanhui Fan,Ming Luo,Huijing Liu,Huifang Han,Fengxian Xie,Xiaoliang Mo,Yingguo Yang,Jia Xu,Alex K.‐Y. Jen,Hong Zhang,Jianxi Yao
出处
期刊:ACS energy letters
[American Chemical Society]
日期:2024-03-05
卷期号:: 1405-1414
标识
DOI:10.1021/acsenergylett.4c00100
摘要
Manipulation of interfacial defects and carrier extraction or transport are crucial for improving the operational stability and photovoltaic performance of perovskite solar cells (PSCs). Here, we propose a technique utilizing bridge molecules to construct a carrier viaduct between perovskite bulk and hole-transporting layers. A molecular bridge configuration combining organic functional groups from each layer was used. The designed bridge molecules not only ensure homogeneous contact and promote carrier extraction/transport but also passivate various defects and redistribute the surface potential. The developed device showed an exceptional power conversion efficiency (PCE) of 25.49% with enhanced operational stability. The treated PSCs could retain over 94% of their initial PCEs after 1000 h of continuous operation under 1 sun illumination and over 95% of their initial PCEs after 500 h of aging at approximately 85 °C in dry air with a relative humidity of 20%. This work provides a simple yet effective approach for fabricating perovskite photovoltaics with outstanding performance and operational stability.
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