Constructing high-energy insensitive fused-ring energetic materials via a strategy of maximizing the heat of formation

The heats of formation of target energetic molecule is up to 4.55 kJ g −1 , which resulted exceptional detonation performance ( D v = 9121 m s −1 , P = 30.1 GPa) and excellent insensitivity (IS > 60 J, FS > 360 N).