Photocatalytic CO2 Reduction with Imidazolium‐based Ionic Liquids

The growing urgency of addressing climate change caused by greenhouse gas emissions and dwindling fossil fuel supplies has heightened the need for effective strategies to capture and utilize carbon dioxide. Photocatalytic CO2 conversion, inspired by natural photosynthesis, presents a viable approach for transforming CO2 into useful C1‐C3 chemical intermediates for industrial purposes. However, the inherent stability of CO2 and the competing hydrogen evolution reaction (HER) introduce significant obstacles. Imidazolium‐based ionic liquids can pre‐activate CO2, accelerate reaction kinetics, and act as eco‐friendly solvents or additives. Systems employing ionic liquids with catalysts, such as homogeneous organocatalysts and heterogeneous materials like Metal‐Organic Frameworks (MOFs) and quantum dots, offer potential solutions to these challenges. This review focuses on the role of ionic liquids in both homogeneous and heterogeneous photocatalytic processes, emphasizing their use in CO2 reduction and highlighting recent mechanistic insights for imidazolium‐based species.