壳聚糖
复合数
孔雀绿
光催化
化学工程
亚甲蓝
材料科学
核化学
化学
可见光谱
复合材料
吸附
有机化学
催化作用
工程类
光电子学
作者
P. Sirajudheen,Sivakumar Vigneshwaran,Nygil Thomas,Manickam Selvaraj,Kumar Venkatesan,Chang Min Park
标识
DOI:10.1016/j.carbpol.2024.122071
摘要
Chitosan (CS) polysaccharide is expected to exhibit greater ionic conductivity, which can be attributed to its increased amino group content when it is blended with different semiconducting materials. Herein, the work use this conducting ability of chitosan and prepared a heterogeneous MoS2-induced magnetic chitosan (MF@CS) composite via co-precipitation method and was used to scrutinize the catalytic performance with Methylene Blue(MB) and Malachite Green (MG) dyes by visible light irradiation. The saturation magnetization value of the MF@CS composite is found to be 7.8 emu/g, which is lesser when compared to that of pristine Fe3O4 (55.7 emu/g) particles. The bandgap of the MF@CS composite is ~ 2.17 eV, which exceeds the bandgap (Eg) of bare MoS2 of 1.80 eV. The maximum color removal of 96.3 % and 93.4 % for MB and MG dyestuffs are recognized in the exposure of the visible spectrum, correspondingly. At a starting dye dosages of 30 mg/L, 0.1 g/L of MF@CS, a pH level of 8 and −11, and 70 min of contact with direct light. The photocatalyst provides extremely good durability for a maximum of five phases. Hence, the MF@CS matrix is a viable and appropriate substance for the efficient treatment of effluents containing dye molecules.
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