离子液体
超级电容器
石墨烯
电化学
电极
材料科学
热解
氧化物
生物炭
化学工程
电容
化学
纳米技术
有机化学
冶金
物理化学
工程类
催化作用
作者
Amirhossein Andooz,Elaheh Kowsari,Mostafa Najafi,Amutha Chinnappan,Maryam Abbasi Eshlaghi,Seeram Ramakrishna
标识
DOI:10.1016/j.electacta.2024.143773
摘要
Graphene oxide (GO) based electrodes often exhibit poor electrochemical performance due to agglomeration. Here, GO was functionalized with the expired heteroatom-rich pharmaceutical compound of Zolmitriptan (ZOL-FGO) as a redox-active spacer to alleviate the mentioned issue. Next, to enhance the electrochemical performance, KOH-activated biochar derived from Heracleum Persicum seeds (HP) through pyrolysis (as a reaction medium) and 1-butyl-3-methylimidazolium tetrachloroferrrate ([Bmim][FeCl4]) ionic liquid (IL) (as a conductivity enhancer) were synthesized and physically composited with the ZOL-FGO. Evaluation of the electrochemical behavior of ZOL-FGO/HP/IL electrode in a three-electrode (3E) system revealed the hybrid supercapacitor nature and recorded a specific capacitance (Cs) of 522 F g−1 at 1 A g−1 and a Cs retention of 97.3% over 10,000 cycles at 8 A g−1. Moreover, the ZOL-FGO/HP/IL//ZOL-FGO/HP/IL electrode was designed and analyzed in the two-electrode (2E) system to determine its practicability. This electrode recorded a Cs of 245 F g−1 at 1 A g−1, a Cs retention of 95.3% over 10,000 cycles at 8 A g−1, and a power density of 900 W kg−1 at the energy density of 41.35 Wh kg−1. The results confirmed that the synergistic effect of the synthesized materials could be promising in constructing a high-performance hybrid supercapacitor.
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