塔菲尔方程
钙钛矿(结构)
过电位
材料科学
储能
电解质
镧系元素
光伏系统
化学工程
氢气储存
光电子学
电极
电化学
化学
复合材料
电气工程
物理化学
离子
合金
物理
有机化学
热力学
功率(物理)
工程类
作者
Shaan Bibi Jaffri,Khuram Shahzad Ahmad,Isaac Abrahams,Ammar M. Tighezza
标识
DOI:10.1016/j.seta.2023.103566
摘要
This work presents the first systematic investigation of the novel [Gd3+–Ho3+-Dy3+]:CsPbI2.2Br0.8 (GHD:CPVSK) hetero-structure and explores it for energy applications. The optical constancy of GHD:CPVSK was explored for 28 days and it spanned around 1.63 – 1.68 eV, expressing remarkable stability in band energy. This material was identified with the cubic phase and possessed typical ABX3 type of crystalline geometry. GHD:CPVSK was used as an absorber layer inside regular perovskite solar cell. It improved the overall photovoltaic operation with the 16.56 % efficiency and 75.89 % fill factor reflecting the excellent perovskite film quality. As an electro-catalyst, the pure hydrogen production activity of GHD:CPVSK excelled over oxygen generation with the lower overpotential and Tafel slope value of 142 mV and 117.3 mV dec−1. Also, this electro-catalyst was electrochemically intact in electrolyte environment for 100 min. In terms of the charge storing capacity for battery, GHD:CPVSK embellished electrode has 470.66 mAh g−1 of unit capacity and impressively minimal equivalent series resistance (Rs) of 0.41 Ω. The developed material stabilized by lanthanide doping has expressed excellency for diverse energy associated applications and systems in a cost effective, facile, and sustainable manner.
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