Poly(Arylene Alkylene)s with Tetrazole Pendants for Alkaline Ion‐Solvating Polymer Electrolytes

Abstract Alkaline ion‐solvating membranes derived from a tetrazole functionalized poly(arylene alkylene) are prepared, characterized and evaluated as electrode separators in alkaline water electrolysis. The base polymer, poly[[1,1′‐biphenyl]‐4,4′‐diyl(1,1,1‐trifluoropropan‐2‐yl)], is synthesized by superacid catalyzed polyhydroxyalkylation and subsequently functionalized with tetrazole pendants. After equilibration in aqueous KOH, the relatively acidic tetrazole pendants are deprotonated to form the corresponding potassium tetrazolides. The room temperature ion conductivity is found to peak at 19 mS cm −1 in 5 wt. % KOH, and slightly declines with increasing KOH concentration to 13 mS cm −1 in 30 wt. % KOH. Based on an overall assessment of the mechanical properties, conductivity and electrode activity, 30 wt. % KOH is applied for alkaline electrolysis cell tests. Current densities of up to 1000 mA cm −2 were reached with uncatalyzed Ni‐foam electrodes at a cell voltage of less than 2.6 V, with improved gas barrier characteristics compared to that of the several times thicker Zirfon separator.