Effects of different types of acid rain on water stability of asphalt pavement

As is known to all, China is one of the countries with more acid rain in the world, and acid rain is mainly distributed in the southern humid climate area of China. However, the construction of semi-flexible asphalt pavement exposed to acid rain environment is a very realistic problem. In order to clarify the influence of different types of acid rain on the water stability of semi-flexible pavement, sulfuric acid type acid rain, nitric acid type acid rain and mixed type acid rain were prepared in this paper, and the semi-flexible specimens were soaked periodically. The water stability of semi-flexible pavement under different types of acid rain corrosion was evaluated macroscopically by standard Marshall test, immersion Marshall test, freeze-thaw splitting test and vacuum saturation test. It was concluded that the Marshall stability, immersion Marshall residual stability, freeze-thaw splitting strength ratio and vacuum saturation residual stability of semi-flexible pavement under different types of acid rain showed different degrees of decline. The reasons for the decline of water stability of semi-flexible pavement under different types of acid rain corrosion were analyzed by scanning electron microscopy and infrared spectroscopy. It was concluded that the acidification condition of rainwater was the main reason for the decrease of ductility, viscosity and plasticity of petroleum asphalt, which affected the binding force between petroleum asphalt and limestone aggregate, and ultimately led to the decline of water stability of semi-flexible pavement. Based on the molecular dynamics theory, the molecular dynamics model of acid rain corrosion asphalt mixture is established. According to the sensitivity of acid components to the main components of semi-flexible asphalt mixture, the asphalt, oil, resin and calcium carbonate with the most content in semi-flexible asphalt mixture are selected to simulate and study. The changes of bonding energy and diffusion coefficient of asphalt mixture under different types of acid rain are calculated and analyzed. It is concluded that sulfuric acid acid rain has the greatest influence on the water stability of semi-flexible specimens, followed by mixed acid rain, and the influence of nitric acid rain is relatively small.