超级电容器
电解质
材料科学
电容
碳纤维
功率密度
碳化
生物量(生态学)
电极
多孔性
化学工程
制作
工艺工程
纳米技术
复合材料
功率(物理)
化学
工程类
扫描电子显微镜
热力学
替代医学
物理化学
病理
地质学
物理
海洋学
复合数
医学
作者
Xiaoguang Liu,Changde Ma,Jiaxin Li,Beata Zielińska,Ryszard J. Kaleńczuk,Xuecheng Chen,Paul K. Chu,Tao Tang,Ewa Mijowska
标识
DOI:10.1016/j.jpowsour.2018.11.032
摘要
The inherent low volumetric performance of two-dimensional (2D) carbon materials hinders their practical usage in portable devices. Three-dimensional (3D) carbon materials derived from sustainable biomass have been widely investigated but also suffer from the moderate volumetric performance. In this work, using biomass (jujube) as carbon precursor, robust 3D porous carbon with a high particle density of 1.06 gcm−3 is synthesized through high-temperature carbonization and subsequent activation. In three-electrode system, the electrode exhibits an ultrahigh volumetric capacitance of 476 Fcm−3 in 6 M KOH electrolyte, which is much higher than previously reported results. The symmetrical two-electrode supercapacitor delivers excellent rate capability (75% capacitance retention at 20 Ag−1) as well as superior cycle stability (91% capacitance retention after 10,000 cycles) in 1 M H2SO4 electrolyte. Furthermore, an energy density as high as 13 WhL−1 at a power density of 477 WL−1 is demonstrated in 1 M Li2SO4 electrolyte. The high volumetric performance of our biomass-derived porous carbon meets the requirements of portable devices and the fabrication process can be scaled up easily to industrial levels.
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