Spatioseasonal Variations and Partitioning Behavior of Organophosphate Esters in the Great Lakes Atmosphere

, but declined with increasing relative humidity. Φ values varied seasonally and were lower in the summer for volatile OPEs. In addition, samples collected in the summer had significantly higher levels of ∑OPEs than samples collected in the winter. The estimated dry deposition flow of ∑OPEs to the Great Lakes was 1.22 tons/year, exceeding the corresponding flows reported for polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs), and organochlorine pesticides (OCPs).