光催化
矿化(土壤科学)
化学
吸光度
水溶液
核化学
电喷雾电离
催化作用
水解
光降解
发光细菌
光化学
色谱法
质谱法
氮气
毒性
有机化学
作者
Bhawna Sarwan,Brijesh Pare,Aman Deep Acharya,Sreekantha B. Jonnalagadda
标识
DOI:10.1016/j.jphotobiol.2012.07.006
摘要
The BiOCl catalyst was prepared by hydrolysis method. The compound was extensively characterized by XRD, SEM, TEM, UV–vis measurements and BET surface area. The prepared material had average pore diameter about 6–13 nm. The BET surface area of the sample is about 40 m2/g. The photocatalytic degradation and toxicity reduction of textile dye neutral red (NR) was investigated in the presence of as prepared BiOCl. The analysis of OH radical formation was performed by fluorescence technique. The intermediates and the final products of degradation were detected by high-performance liquid chromatography–photodiode array-electrospray ionization-mass spectrometry (HPLC–ESI-DAD-MS) technology. Decrease in chemical oxygen demand (COD) and dye absorbance of the photodegraded dye solution revealed a complete mineralization of NR into CO2 and inorganic ions. The recycling experiments confirmed the relative stability of the catalyst. Finally, the luminescent marine bacteria Vibrio fischeri was used to assess the acute toxicity of samples prior to and after the photocatalytic treatment and it was found that toxicity was fully eliminated following photocatalytic degradation.
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