化学
配体(生物化学)
结晶学
水热合成
热液循环
氮气
硫酸盐
氧原子
立体化学
分子
有机化学
化学工程
生物化学
工程类
受体
作者
Robert L. LaDuca,Randy S. Rarig,Pamela J. Zapf,Jon Zubieta
标识
DOI:10.1016/s1293-2558(00)00110-2
摘要
Hydrothermal synthesis has been exploited in the preparation of two new materials of the Ag(I)-organodiimine class of materials. By exploiting variations in ligand geometry and tether length and the structural influence of different oxoanions, the inorganic oxides [Ag(dpe)(NO3)](dpe=1,2-bias(4-pyridyl)ethane) and [Ag2(2,4′-bpy)2(SO4)(H2O)]·5H2O(2·5H2O) were isolated. Compound 1 was prepared in the reaction of Ag(NO3), dpe, and H2O in the mole ratio 1:1:500 at 120°C for 24 h, while compound 2 was prepared from Ag2SO4, 2,4′-bpy, and H2O under similar conditions. The structure of 1 is constructed from {Ag(dpe)}nn+ chains linked through η2, μ2–NO3− groups into a two-dimensional network. The structure of 2·5H2O consists of one-dimensional sinusoidal chains. The Ag(I) sites exhibit two distinct geometries: one is ‘T’-shaped through bonding to two nitrogen donors from two 2,4′-bpy groups and a sulfate oxygen; the second site is also ‘T’-shaped through bonding to two pyridyl nitrogen atoms and an aqua ligand.
科研通智能强力驱动
Strongly Powered by AbleSci AI