化学
催化作用
密度泛函理论
溶剂
组合化学
氧气
反应机理
计算化学
有机化学
光化学
作者
Xingyu Chen,Sixian Lu,Yuyan Yan,Jigang Wang,Yang Liu,Peng Sun
标识
DOI:10.1002/adsc.202101444
摘要
Abstract Herein, we have established a method for the construction of β‐keto sulfones through aerobic oxy‐sulfonylation of alkynes with sulfinates. The reaction performed employing air as the oxidant and oxygen source. Moreover, this protocol exhibits low consume of sulfinates, short reaction period, and minimal waste. Mechanism study and density functional theory (DFT) calculation showed that the solvent played a significant role in the transformation. magnified image
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