塞曼效应
凝聚态物理
单层
掺杂剂
物理
磁场
退化(生物学)
自旋(空气动力学)
兴奋剂
化学
原子物理学
纳米技术
材料科学
量子力学
生物
热力学
生物信息学
作者
Qi Li,Xiaoxu Zhao,Longjiang Deng,Zongjun Shi,Sheng Liu,Qilin Wei,Linbo Zhang,Yingchun Cheng,Haipeng Lu,Weibo Gao,Wei Huang,Cheng‐Wei Qiu,Gang Xiang,Stephen J. Pennycook,Qihua Xiong,Kian Ping Loh,Bo Peng
出处
期刊:ACS Nano
[American Chemical Society]
日期:2020-03-13
卷期号:14 (4): 4636-4645
被引量:70
标识
DOI:10.1021/acsnano.0c00291
摘要
The “Zeeman effect” offers unique opportunities for magnetic manipulation of the spin degree of freedom (DOF). Recently, valley Zeeman splitting, referring to the lifting of valley degeneracy, has been demonstrated in two-dimensional transition metal dichalcogenides (TMDs) at liquid helium temperature. However, to realize the practical applications of valley pseudospins, the valley DOF must be controllable by a magnetic field at room temperature, which remains a significant challenge. Magnetic doping in TMDs can enhance the Zeeman splitting; however, to achieve this experimentally is not easy. Here, we report unambiguous magnetic manipulation of valley Zeeman splitting at 300 K (geff = −6.4) and 10 K (geff = −11) in a CVD-grown Fe-doped MoS2 monolayer; the effective Landé geff factor can be tuned to −20.7 by increasing the Fe dopant concentration, which represents an approximately 5-fold enhancement as compared to undoped MoS2. Our measurements and calculations reveal that the enhanced splitting and geff factors are due to the Heisenberg exchange interaction of the localized magnetic moments (Fe 3d electrons) with MoS2 through the d-orbital hybridization.
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