材料科学
电介质
复合材料
陶瓷
物理
分析化学(期刊)
凝聚态物理
化学
量子力学
色谱法
作者
Yan Gu,Faqiang Zhang,Wanghua Wu,Zhifu Liu
标识
DOI:10.1142/s2010135x23500029
摘要
Most widely used dielectrics for MLCC are based on BaTiO 3 composition which inevitably shows performance degradation during the application due to the migration of oxygen vacancies ([Formula: see text]). Here, the BaTiO 3 , (Ba[Formula: see text]Ca[Formula: see text])TiO 3 , Ba(Ti[Formula: see text]Mg[Formula: see text])O 3 , (Ba[Formula: see text]Ca[Formula: see text])(Ti[Formula: see text]Mg[Formula: see text])O 3 , (Ba[Formula: see text]Ca[Formula: see text]Dy[Formula: see text])(Ti[Formula: see text]Mg[Formula: see text])O 3 ceramics (denoted as BT, BCT, BTM, BCTM and BCDTM, respectively) were prepared by a solid-state reaction method. The core-shell structured grains ([Formula: see text]200 nm) featured with 10-20 nm wide shell were observed and contributed to the relatively flat dielectric constant-temperature spectra of BTM, BCTM and BCDTM ceramics. The TSDC study found that the single/mix doping of Ca[Formula: see text], especially the Mg[Formula: see text], Mg[Formula: see text]/Ca[Formula: see text] and Mg[Formula: see text]/Ca[Formula: see text]/Dy[Formula: see text] could limit the emergence of during the sintering and suppress its long-range migration under the electric-field. Because of this, the highly accelerated lifetimes of the ceramics were increased and the value of BCDTM is 377 times higher than that of BT ceramics. The [Formula: see text] junction model was built to explain the correlation mechanism between the long-range migration of and the significantly increased leakage current of BT-based dielectrics in the late stage of HALT.
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