Chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with improved mechanical and photo-thermal conversion properties via tuning CuSNPs' morphological structures

Conventional textiles are inadequate for maintaining warmth in extremely cold conditions. Therefore, the development of photo-thermal fibers for personal thermal management textiles has emerged as an urgent need. Herein, novel chitosan/copper sulfide nanoparticles (CS/CuSNPs) hybrid fibers with photo-thermal function were fabricated successfully. Significantly, our study demonstrated that the tensile and photo-thermal conversation properties of the CS/CuSNPs hybrid fibers could be effectively regulated by altering the CuSNPs` morphological structures. Compared with other CuSNPs (tube-like, sphere-like, and flower-like), the plate-like CuSNPs with smooth surfaces and uniform nanometer size played a significant role by scattering incident light in the fibers as a secondary light source for CuSNPs absorbance. Thus, under IR light irradiation at a power density of 1.0 W/cm2, the surface temperature of CS/0.1 wt% plate-like CuSNPs hybrid fibers sharply increased by 27.6 °C, which was more than 4 times of the pure CS fibers. And the breaking strength and initial modulus of CS/0.1 wt% plate-like CuSNPs hybrid fibers increased by more than 18.37 and 6.88 % compared with the nascent CS fibers. This study develops a novel and effective strategy to tune the photo-thermal and tensile properties of CS hybrid fibers without incorporating more content or additives.