分子筛
摩尔比
硅
协调数
化学
化学工程
催化作用
材料科学
无机化学
结晶学
有机化学
离子
工程类
作者
Lei Xu,Aimin Du,Yingxu Wei,Yingli Wang,Zhengkun Yu,Yanli He,Xinzhi Zhang,Zhongmin Liu
标识
DOI:10.1016/j.micromeso.2008.02.001
摘要
SAPO-34 molecular sieves with different Si coordination environment were synthesized by adjusting SiO2/Al2O3 molar ratio in starting gel. The crystal structure, element composition and Si coordination environment of the as-synthesized samples were characterized by XRD, SEM, XRF and NMR. SAPO-34 molecular sieve could be obtained when the SiO2/Al2O3 molar ratio of the starting gel was higher than 0.075. The content and modeling of Si incorporated into SAPO-34 framework varied with the SiO2/Al2O3 molar ratios in the starting gel and different Si chemical environments were formed correspondingly. SAPO-34 with only Si(4Al) coordination structure could be prepared when the SiO2/Al2O3 molar ratio of the starting gel was in range of 0.075–0.15.
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