材料科学
聚氨酯
多元醇
热塑性聚氨酯
极限抗拉强度
热塑性塑料
聚酯纤维
生物高聚物
异佛尔酮二异氰酸酯
高分子化学
化学工程
复合材料
弹性体
聚合物
工程类
作者
Jiyeon Oh,Young Kwang Kim,Sung‐Ho Hwang,Hyunchul Kim,Jae‐Hun Jung,Cho‐Hyun Jeon,Sang Kyoo Lim
摘要
Abstract The study involved producing green thermoplastic polyurethanes (TPUs) that were either partially or fully bio‐based. This was achieved through a one‐shot polymerization process using a combination of sebacic acid‐polyester polyol, 1,4 butanediol derived from renewable sources, and diisocyanate. The diisocyanate used included bio‐aliphatic pentamethylene diisocyanate (PDI), petro‐aromatic methylene diphenyl diisocyanate (MDI), and a combination of PDI and MDI. Various methods were employed to characterize the newly synthesized TPUs, which had a weight average molecular weight exceeding 120,000 g/mol. Increasing the content of PDI improves the bio‐based carbon content up to about 97% and increases the pyrolysis onset temperature. An increase in MDI content results in a rise in the complex viscosity, tensile strength, and strain. However, a PDI‐based TPU (P/M_100/0) achieved an excellent phase separation with a tensile strength of 20.7 MPa and elongation of 587.2%, comparable to an MDI‐based TPU (P/M_0/100). Overall, this research demonstrates the feasibility of utilizing partially or fully bio‐based TPUs as a substitute for conventional MDI, with potential industrial applications.
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