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Boosting fenton-like reaction by reconstructed single Fe atom catalyst for oxidizing organics: Synergistic effect of conjugated π-π sp2 structured carbon and isolated Fe-N4 sites 相关领域
催化作用
共轭体系
过氧二硫酸盐
化学
氧化剂
分解
激进的
吸附
碳纤维
光化学
分子
无机化学
组合化学
材料科学
有机化学
聚合物
复合材料
复合数
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| 其它 | The synthesis of a highly efficient and stable single atom catalyst (SAC) for peroxydisulfate (PDS) activation remains a challenge. Herein, a reconstructed iron single atom catalyst (Fe-SAC) with both abundant conjugated π-π sp2 structured carbon and reactive Fe-N4 sites was first reported to improve the decomposition of organics in PDS/SACs systems. Enhanced organics adsorption can be achieved by the conjugated π-π sp2 structured carbon via π-π interaction to decrease the migration distance of reactive species to organic molecules. In addition, PDS tended to be attached onto the Fe-N4 sites accompanied by the peroxymonosulfate (PMS) generation via S-O breakage of PDS, accelerating the generation of radicals. |
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(2025-6-4)