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Unlocking iron-based mixed-phosphate cathode for sodium-ion batteries through off-stoichiometry Research 相关领域
化学计量学
磷酸铁
阴极
磷酸盐
钠
离子
无机化学
材料科学
化学
化学工程
物理化学
冶金
有机化学
工程类
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| 其它 | The off-stoichiometric iron-based phosphate (Na3.12Fe2.44(P2O7)2, denoted as Na3.12) as a low cost and high structure stability cathode material has been widely studied for sodium-ion batteries (SIBs). However, the lower theoretical specific capacity (117 mAh·g−1) has seriously limited its practical application. In this work, we incorporate varying proportion of sodium-iron phosphate (NaFePO4) into the Na3.12 to form a series of new high specific capacity mixed-phosphates Na3.12+xFe2.44+x(P2O7)2(PO4)x cathode materials for SIBs. |
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(2025-6-4)