烘烤
锰
尖晶石
阴极
热液循环
电化学
材料科学
化学工程
电解质
冶金
无机化学
化学
电极
物理化学
工程类
作者
Lirong Huang,Xiaoqin Li,Junjie Hu,Qiang Deng,Chenghao Yang,Weizhen Liu,Feiping Zhao,Hao Jiang
标识
DOI:10.1016/j.seppur.2023.126248
摘要
Recovering high-value-added Mn products from electrolytic manganese residue (EMR) is prominent due to the scarcity of Mn resource and its increasing importance in various industries. In this study, we explored Mn and Mg recovery from EMR for the synthesis of cathode material MgMn2O4 for the first time through Na2CO3 hydrothermal-roasting method. Na2CO3 concentration and roasting temperature were found to significantly affect the morphology and structure of MgMn2O4. Both flower-like MgMn2O4 (f-MMO) and hollow MgMn2O4 (h-MMO) were synthesized under optimized conditions. Additionally, the electrochemical performances of MgMn2O4 as cathode material of magnesium-ion batteries were evaluated. Both f-MMO and h-MMO showed superior rate performance. High initial reversible capacity can be achieved (237.5 mAh/g), and still retain 157.7 mAh/g after 40 cycles at 100 mA/g and 76 mAh/g after 500 cycles at 500 mA/g. This work inspires the way for recovering Mn from EMR as energy storage material.
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